The Weizmann Institute of Science today announced that a research group headed by Dr. Ernesto Joselevich has developed a new approach to create patterns of carbon nanotubes by formation along atomic steps on sapphire surfaces. Carbon nanotubes are excellent candidates for the production of nanoelectronic circuits, but their assembly into ordered arrays remains a major obstacle toward this application.
The team was initially researching in a different direction: they were trying to give carbon nanotubes (structures reminiscent of rolled-up sheets of graphite) a preferred orientation on a wafer by applying an electrical field as the tubes were being formed. This works very well with silicon dioxide wafers. On a sapphire support (sapphire is a form of aluminum oxide), on the other hand, it didn’t work: the nanotubes were beautifully arranged in parallel, but with an orientation that was completely independent of the electrical field - even when no field was applied at all!
Closer examination of the sapphire surface solved the mystery: commercial sapphire wafers are generally not cut exactly along the plane of the crystal. Their surface is thus not completely smooth; instead, it has parallel steps - of atomic dimensions - between the different planes of the crystal. The nanotubes wind up lying along these steps. The researchers explain it like this: the nanotubes form from a catalyst of iron nanoparticles and are attracted to a local field created by the steps. It is clear that these iron particles don’t like “climbing stairs;” instead, they “glide” along the inner edge of the step, like on a track. They thus remain continuously in contact with two surfaces, rather than just one, which seems to stabilize the catalyst. Just as an airplane leaves behind a condensation trail, the iron particles leave the newly formed nanotubes lying along their “tracks.” The nanotubes even follow kinks in the steps, which are caused by defects in the crystal. This results in either straight or zigzag-shaped tubes, which are expected to have particularly interesting electronic properties.
“The orientation and form of the atomic steps on a crystal surface can be controlled by the cutting process, and defects can be created artificially,” says Joselevich. “It should thus be possible to produce different nanowire arrangements in a controlled fashion.”
Dr. Joselevich’s findings appear this week as the cover story of Angewandte Chemie.
Dr. Joselvich's research is supported by the The Asher and Jeannette Alhadeff Research Award, the Ilse Katz Institute for Material Sciences and Magnetic Resonance Research, the Philip M. Klutznick Fund for Research, Sir Harry A.S. Djanogly, CBE, UK and Sylvia and Henry Legrain, Spain. He is the incumbent of the Dr. Victor L. Ehrlich Career Development Chair.