Getting the Oil Out

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Dr. Ishai Dror and Prof. Brian Berkowitz. Getting the oil to flow
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Part family saga, part invention that might help extend the world’s oil reserves for many years to come, the story of a patent for a method of extracting usable oil from so-called oil sands has all the elements of a "tragedy-to-bittersweet success" movie.

The story begins with Prof. Norbert Berkowitz, father of the Weizmann Institute’s Prof. Brian Berkowitz, who was a highly respected coal chemist at the University of Alberta in Edmonton, Canada. The northern part of Alberta, one of Canada’s western provinces, contains enormous deposits of oil in its oil sands. The problem is that the oil in these deposits is more like thick tar than a gushing liquid, making it impossible to simply sink a well and pump the stuff up. This oil is presently dug up and diluted with large amounts of solvent, or even larger amounts of a thinner oil, so it can be piped to refineries hundreds and thousands of kilometers away. But these methods are expensive and problematic, severely limiting the extraction potential of these fields.

Norbert Berkowitz had an idea for turning the viscous gunk from oil sands into flowing oil, using water. He and his Calgary-based business partner, Stephen Dunn, applied for a patent for the process in Canada. But they needed to test the idea, and Norbert, who was retired at that point, did not have immediate access to a lab. Before he got the chance to begin carrying out experiments on his idea, he and his wife, Sheila, were tragically killed in an auto accident in 2001.

Dunn met Brian and his siblings in Edmonton, where they had gathered soon after the accident, and gave them a copy of the patent application as a family keepsake. Then and there, Brian promised he would take up where his father had left off and see the project to fruition. For Brian, whose area of research is hydrology, this involved first and foremost a crash course in hydrocarbon chemistry. Even with some knowledge of petroleum engineering (which he’d picked up some 20 years earlier during his M.Sc. studies), he needed specialized knowledge to carry on with the project. Fortunately, his father had written three books and dozens of scientific papers on the subject, and these became Berkowitz’s study guides, inspiring him to delve more deeply into the basic science behind the idea. For Brian, touching and reading these books was "both magical and intensely painful."

When the time came to build the actual apparatus in his lab in the Environmental Sciences and Energy Research Department with the help of then post-doctoral fellow Ishai Dror, it took two and a half years to plan, construct and test an experimental system. "We had to design everything ourselves, from the screws on up," says Berkowitz. The process then had to be fine-tuned. "Cook" it too long, and instead of free-flowing oil the result is coke, a sort of low-grade coal. More than once, Berkowitz found himself covered in oil from small explosions, and the lab walls had to be repainted. After countless late nights in the lab and dozens of nights spent reading and thinking, the day finally arrived when the oil, in a cinematic "Eureka!" moment, began to flow like milk.

Berkowitz’s father had come up with a way to create a system that could potentially extract a large amount of oil quickly and efficiently. The process relies on water that is heated under pressure. Although it had been known for some time that a hot "supercritical liquid" could be used to partially break down viscous oil, the new system translates this knowledge into a practical, flow-through apparatus that doesn’t require a long heating period. A supercritical liquid is neither a liquid nor a gas, but a substance that has properties of both, plus some atypical properties as well. It occurs at high pressures and temperatures: As the pressure goes up, the boiling point of water rises and the water remains liquid, even at temperatures well above 100° C (212° F). Oil won’t dissolve in either water or steam, but supercritical water can be used as a solvent for all kinds of oil. In the case of the thick oil from oil sands, the supercritical water reacts chemically with the long hydrocarbon chains that cause the oil to be so viscous, breaking them into shorter ones that flow past each other more easily.

As well as the original patent (now handled by Yeda, the business arm of the Weizmann Institute), which has been expanded with add-ons that have come out of Berkowitz’s research, a four-country patent has been applied for under the aegis of Yeda. In addition to Canada, other countries - among them Venezuela - have extensive oil sands and heavy oil deposits that could potentially be exploited with the method

The final scene in the movie is yet to come: Norbert Berkowitz’s business partner, Stephen Dunn (who has since become Brian’s friend and business partner), recently signed an agreement with Yeda to build a demonstration plant in Calgary. Hopefully, as the partners ride off into the sunset, it will be in a car fueled with plentiful Canadian heavy oil.  

Prof. Brian Berkowitz's research is supported by the Sussman Family Center for the Study of Environmental Sciences; the Brita Fund for Scholarships Research and Education; the Feldman Foundation; the P. and A. Guggenheim-Ascarelli Foundation; and Mr. and Mrs. Michael Levine, Pinckney, NJ. Prof. Berkowitz is the incumbent of the Sam Zuckerberg Professorial Chair in Hydrology.
 
(l-r) Dr. Ishai Dror and Prof. Brian Berkowitz. Taking up the challenge
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Unofficial Liaison

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Dr. Tareq Abu Hamed, daughter Ilia and wife Sukina in Sur Baher
 

 

 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Dr. Tareq Abu Hamed, from the village of Sur Baher, near East Jerusalem, is a great believer in the ability of science to bridge cultural, social and political gaps. While completing his Ph.D. in chemical engineering at Ankara University in Turkey, Dr. Abu Hamed became interested in conducting post-doctoral research in the Environmental Sciences and Energy Research Department at the Weizmann Institute. He was attracted to the Institute by its reputation for world-class research and such resources as the solar tower, one of the most advanced facilities in the world for solar energy research. “To me this was a natural choice,” says Abu Hamed. “I wanted to choose a path where I could realize my full potential.”
 
Despite the general political climate and the tensions between Palestinians and Israelis during the heat of the Intifada, Abu Hamed found the Institute welcoming: “People here are kind and easy-going, yet professional and accomplished. They're busy with science, and nothing interferes with that.” His adviser, Prof. Jacob Karni, says: “Naturally, people at the Weizmann Institute come from a broad spectrum of cultural, ethnic and political backgrounds. These differences are all completely irrelevant to our work.” “Many Palestinians don't want any sort of cooperation with Israel,” says Abu Hamed, “but for Palestinian students and researchers, it’s worthwhile becoming involved in the scientific community in Israel and taking part in the high-level, challenging science here.”
 
In Abu Hamed's youth he learned the value of communication in achieving common goals. As a teenager living in a small village on the West Bank-Israeli border, he spent his summers picking fruit on nearby kibbutzim. There he worked side by side with people from all over the world, learning and practicing English, and discovering other cultures. Abu Hamed describes himself as a sort of an unofficial cultural liaison: “By mixing with foreign visitors, I hoped to gain an understanding of other views and to influence the perceptions of those who live in Israel.”
At the Institute, as well, he often finds himself at the interface between Israelis, Palestinians and members of the international research community: “My Israeli friends often question me about the Palestinian point of view.” His personal beliefs, however, don’t always coincide with the Palestinian viewpoints most often reported in the press. The promotion of scientific cooperation between Israelis and Palestinians is more important to him than politics, and he believes this ideal should be fostered from the earliest elementary school levels. Since joining the Institute, he has organized tours of the Clore Garden of Science on the Weizmann campus for Palestinian children attending summer programs in his village. He sees himself as a role model for the children and their teachers as he accompanies the groups, explaining the scientific principles involved in the Garden’s interactive exhibits.
 
Abu Hamed would like to see all sorts of exchange programs instituted, in which Israeli and Palestinian lecturers, scientists and teachers would spend time with their colleagues and counterparts. “Beginning with one person and growing to 100, we need to work together for science education. To me, it was a shock that Dr. Sari Nusseibeh, President of Al-Quds University, received such severe criticism from the Palestinian scientific community for his initiative in signing an agreement with the Hebrew University.” Abu Hamed believes that “the future holds more cooperation, but it will require change and a new generation willing to support it. We’ll succeed if we truly want it and refuse to give up.” 

 

Alternative Fuel Holds Water

 

From solar energy to fuel

 

 

 

 

 

 

 
 
 
Five kg (11 lbs) of hydrogen is sufficient to fuel an average car for 500 km (311 mi), and there are no CO2 emissions. Hydrogen can be extracted from water, using a somewhat tricky technique, but researchers have been most challenged to find a solution for hydrogen storage. In a recent study appearing in the Solar Energy Journal, Dr. Tareq Abu Hamed, Prof. Jacob Karni and Michael Epstein, Head of the Solar Resources Facility, explore the use of boron, a lightweight semimetallic element, as a novel solution for onboard hydrogen storage and fuel production.
 
Abu Hamed: “Boron and water can be stored separately in two containers. Mixing them in a controlled fashion will release hydrogen as demanded by the engine.” The only byproduct is boron oxide, which is neither spent nor wasted: The boron can be separated from the oxygen in a process powered by solar energy and reused again and again for automotive hydrogen production.
 
“It's safe,” says Abu Hamed, “mostly involving materials that are harmless and relatively simple to handle.” The team plans to construct a working system in the near future to test the theoretical findings of this study.
 
Dr. Tareq Abu Hamed, daughter Ilia and wife ukina. Warm welcome
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Here Comes the Sun

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Dr. Mahmoud Huleihil. Keeping the mirrors true
 
 
Not everyone gets the opportunity to work at his passion. Even as a child in Safed, one of the oldest cities in Israel, Mahmoud Huleihil treasured the purity of his natural surroundings. As an adult, he ventured to another pristine place, Sde Boker in the Negev desert, where he performed research on solar energy. What attracts him to that particular kind of energy? "It's pure," he says, as if this should be obvious to anyone who would compare a day on the beach to a walk in a smog-filled city.

But it's purely expensive, too. Arriving six months ago as a postdoctoral fellow at the Weizmann Institute, Dr. Mahmoud Huleihil of the Environmental Sciences and Energy Research Department is working to solve this kink in solar energy. "We've got to convince politicians," says Dr. Huleihil, "...and that's usually done through the pocketbook."

The divisive factor is the construction of a new solar power plant: Why invest money in building an additional plant when the old system works just fine, thank you? Simulating solar power plant construction on his computer, and programming it to suit experimental needs, the objective is to bring cost, as well as sunlight, down to earth.

The heliostat, a type of mirror, accounts for about 50 percent of the plant's total cost, according to senior scientist Dr. Abraham Kribus, Dr. Huleihil's postdoctoral advisor. [Dr. Kribus holds the Recanati Career Development Chair of Energy Research.] Maximizing the mirrors' efficiency will make it possible to minimize their cost. The solar plant's field area, occupied principally by the mirrors, would shrink proportionately.

One of Huleihil's challenges is to address the mirrors' tendency to deviate slightly from their set position. When this happens, the mirrors miss their target: the solar receiver, which absorbs their sum energies. But in a field of hundreds of mirrors, how can you find the one that's "faking" it?
 
The computer, which sets the mirrors' angles according to the time of day, can't tell the difference; judging by its screen, you wouldn't even know anything was amiss. Solution: Dr.Huleihil is working on a computer program which will spot deviant behavior by calculating the different light intensities shone on four "smart cameras" placed around the receiver.

Solar energy may, in fact, be even more efficient than other forms of energy. One of the basic precepts of thermodynamics is this: The higher the temperature, the greater the efficiency. The sun's temperature is approximately 6,000° C (10,832° F). Using solar energy, scientists can draw the sun's heat to earth at a temperature of 2,000° C (3,632° F), much higher than the temperature obtained when heating with fossil fuel. (Preliminary calculations to determine whether using solar energy in this way is worthwhile are currently being carried out by Weizmann scientists.) Yet, even with its advantages in mind, solar energy is costly.

However, as Dr.Huleihil points out, in assessing the price of an energy source, one must not look only at the accounts book ­ one must look at nature and the environment as well.
 
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The Sun Rises on a Pilot Power Project

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Pilot solar plat design


A unique pilot solar power plant is about to be set up at the Weizmann Institute. Its construction is the first step in a large-scale U.S.-Israel project whose ultimate goal is to build commercial solar power stations throughout the world.

The project's participants are America's McDonnell Douglas and Israel's Ormat Industries Ltd., Rotem Industries Ltd. and the Weizmann Institute -- through its commercial arm, Yeda Research and Development Co. They have been awarded $5.3 million by the U.S.-Israel Science and Technology Commission to jointly demonstrate the commercial feasibility of an advanced solar power plant capable of generating anything from hundreds of kilowatts to tens of megawatts of power. The signing of the collaboration agreement was announced on March 10 at the U.S. Space and Rocket Center in Huntsville, Alabama.

The U.S.-Israel Science and Technology Commission was set up in 1994 by President Clinton and the late Prime Minister Rabin to enhance cooperation and create technology-based jobs for the 21st century. It was within this framework that the McDonnell Douglas-Rotem-Ormat collaboration was initiated.

The novel American-Israeli system uses special optics and an innovative air receiver developed by the Weizmann Institute. These reflect, concentrate and convert sunlight to provide the high temperatures necessary to directly power gas and steam turbines in a combined cycle and thus generate electricity.

The ability to operate on either solar power, gas, or a combination of solar power and gas, will provide operational flexibility and guarantee electricity even during inclement weather. The application of combined cycles ensures very high efficiency in all modes of operation. Recent market assessments indicate that this new technology has the potential for wide international applications.

In less than three years, the American-Israeli team will develop an operational 200-300-kilowatt system to be located at the Weizmann Institute's solar research facility, known as the Canadian Institute for the Energies and Applied Research. This pilot system will use some of the facility's highly reflective mirrors, or heliostats, which track the sun. These heliostats will reflect sunlight up to a new reflector to be installed atop the Institute's solar tower. This reflector will then redirect the sunlight back down to a matrix of optical concentrators, capable of concentrating the light 5,000 to 10,000 times, as compared to natural sunlight reaching the earth. The concentrated radiation will then enter a group of solar receivers, located on the ground, which will heat up compressed air to be used for driving the turbogenerator that produces electricity.

The pilot system's advantages stem from a unique combination of technologies. First, the production facilities, including the concentrators, receivers and turbogenerator, are located on the ground rather than at the top of the tower, making construction of the tower significantly simpler and cheaper.

Second, the sophisticated design of the concentrators, based on pioneering research at the Weizmann Institute, will make it possible to concentrate sunlight sufficiently to heat the air to the temperature needed for driving advanced gas turbines.

A third innovation is the use of the Weizmann Institute-designed solar receiver (nicknamed "Porcupine") which contains hundreds of ceramic pins arranged in a geometric pattern that maximizes the collection and use of sunlight. Compressed air that flows across the pins is heated and channeled to the gas turbines. Sunlight enters the device through a special cone-shaped quartz window that can withstand higher pressure than can a similarly designed steel cone.

Many of the new technologies originated at the Institute. Following the initial stages of the research, the Institute scientists were joined by experts from Rotem Industries, who collaborated with Weizmann on the design and construction of the first prototype of the "Porcupine" receiver, as well as on consolidating the design of its optical components. Most of the research conducted up to this stage was supported by the Chief Scientist of Israel's Ministry of Energy (now the Ministry of National Infrastructures).

When the research reached a relatively advanced stage, Consolar Ltd. -- a consortium of Israeli companies and academic institutions -- was established comprising Rotem Industries, Ormat Industries, Silver Arrow, the Israel Aircraft Industries, the Weizmann Institute of Science, Tel Aviv University and Ben-Gurion University of the Negev. It is supported by the Chief Scientist of Israel's Ministry of Industry and Trade, under the Ministry's Magnet program, whose aim is to promote the application of new and emerging technologies.
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Fill It Up... With Hydrogen

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Hydrogen, the lightest and most prevalent element in the universe, may prove to be the car fuel of choice in the future.

Tests on experimental vehicles have already shown hydrogen to be an efficient and pollution-free fuel; now Institute researchers are working on reducing the prohibitive cost involved in its production. They are developing technology that will use solar energy to extract hydrogen from its most readily available source, water.

Water molecules, which contain two atoms of hydrogen and one of oxygen, break apart when heated to very high temperatures under low pressure. But until now the hydrogen could not be exploited because the elements quickly recombine once they cool down.

Now a method to keep the elements separate has been developed by Prof. Avraham Kogan, working at the Institute's Solar Research Facilities Unit. In collaboration with the Israel Ceramic and Silicate Institute, he designed a special ceramic membrane that withstands temperatures of more than 2,000°C and allows hydrogen atoms to pass through while leaving the larger oxygen atoms behind. Kogan says the method is feasible, but the membrane has to work at even higher temperatures for it to be economically viable.
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Institute Solar Project given American-Israeli Support

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Ron Brown and Micha Harish give the project their blessings

An $8-million solar energy project to be carried out by Weizmann Institute researchers together with U.S. and Israeli companies is one of the three binational undertakings recently selected for support by the U.S.-Israel Science and Technology Commission, which evaluated over 100 proposals. Final approval of the project is contingent upon the results of a $100,000 feasibility study, now under way.

The project's goal is to develop a solar power plant that will produce electricity at competitive prices. About half the cost of the development is to be provided by the Commission, while the companies involved will supply the rest.

"We selected three future-oriented projects that can meet immediate needs and provide a basis for long-term economic growth and job creation in both the United States and Israel," U.S. Secretary of Commerce Ronald Brown said at the Jerusalem ceremony where the winners of the Commission's first grants program were announced.

The Weizmann Institute will participate in the project via Yeda Research and Development Company, which is responsible for commercialization of Institute research. The industrial partners are McDonnell Douglas Aerospace of the U.S. and Israeli companies Ormat, Elop and Rotem. The Weizmann contribution consists of developing novel high-concentration solar technologies, including an air receiver, as well as innovative optical and energy storage facilities. These will be based on campus research carried out in recent years at the Canadian Institute for the Energies and Applied Research and the Schaefer Solar Research Complex.

According to conservative estimates, the solar installations to be developed are expected to generate $1.4 billion in sales by the year 2005. By 2010, they may account for 660 megawatts of electricity worldwide. In addition to helping clean up the environment by reducing the need for polluting fossil fuels, they also offer the opportunity of converting defense technologies to civilian use.
Environment
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China Follows the Sun to Israel's Weizmann Institute

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Chinese researchers and Prof. Amnon Yogev. Exporting knowledge

The giant People's Republic of China is looking to the Weizmann Institute of Science in tiny Israel to provide it with some of the know-how it requires for developing advanced solar technology.


In pursuit of this goal, the Chinese Academy of Sciences has sent to the Institute two researchers, Kou Qing and Yao Chengcai, who point out that their country's growing interest in solar energy is spurred by the difficulties it faces in supplying its huge population with electricity, as well as by its mounting concern over pollution caused by burning fossil fuels.

Kou, 26, is from the Institute of Electrical Engineering in Beijing, an affiliate of the Chinese Academy of Sciences and China's foremost energy research facility. It has recently helped establish the first of 10 solar power plants scheduled to be built in Tibet, where fossil fuels are scarce and many villages still have no electricity.

Of particular interest to Kou is the development of systems based on solar cells that use concentrated sunlight at selected spectral bands. In a research project supervised by Prof. Amnon Yogev, Head of Weizmann's Energy Research Center, he is trying to determine which part of the sun's spectrum is most suitable for operating such cells. After returning to China, Kou, who is learning Hebrew in his free time, hopes to initiate collaboration between the Weizmann and his Institute in Beijing.

Yao, 28, who was sent here together with Kou in January 1993, is a researcher and lecturer in solar engineering at the University of Science and Technology of China (USTC), a top Chinese institution located in Hefei, some 2,000 km south of Beijing. Now claiming Yao's attention is a research project headed by Michael Epstein, Director of the Solar Research Facilities Unit. The aim of the study is to transform solar energy into storable and transportable chemical fuel that can be used hundreds of miles away from where the sun's rays are collected.

Yao is the eldest son of peasants in southern China, who couldn't afford to send all of their five children to school, so that one of them wound up with just two years of formal education. Yao managed to finish high school and enter university, which at the time was free for talented children from indigent families.

The Weizmann assignment makes him the pride of his parents' entire village, Yao says. When he goes home, he intends to teach his students everything he learned at the solar tower.

Prof. Yogev holds the Stephen and Mary Meadow Chair of Laser Photochemistry.
 
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